Tunable Polariton Canalization in Natural van der Waals Oxide

Abstract: Hyperbolic phonon polaritons (HPPs) are coupled oscillations of anisotropic lattice vibrations and electromagnetic fields that confine the latter to the nanoscale, enabling novel nano-polaritonic devices. While HPPs have been identified in multiple layered materials, achieving advanced control and manipulation - particularly polariton canalization for unidirectional energy flow - often necessitates complex device fabrications or crystal modifications. Here we visualize and elucidate the properties of in-plane hyperbolicity in alpha-V2O5, a layered compound with a highly anisotropic permittivity tensor. We show unidirectional Poynting-vector propagation of polaritons in alpha-V2O5 without additional treatments. Combined with theoretical modeling, our infrared nano-imaging studies unveil a novel form of polariton canalization, with its dispersion contour continuously tunable by the incident light frequency. Additionally, we provide a theoretically calculated permittivity phase diagram for tailoring polaritonic wavefronts. These findings suggest that the metal-oxide alpha-V2O5 holds great promise for on-demand light canalization and control at the nanoscale.