Time-resolved spectroscopy with entangled photons

Abstract: Interaction of light with media often occurs with a femtosecond response time. Its measurement by conventional techniques requires the use of femtosecond lasers and sophisticated time-gated optical detection1-3. Here we demonstrate that by exploiting quantum interference of entangled photons it is possible to measure the phase relaxation time of a media on the femtosecond time scale (down to 100 fs) using accessible continuous wave laser and single-photon counting. We insert the sample in the Hong-Ou-Mandel interferometer4 and infer the phase relaxation time from the modification of the two-photon interference pattern. In addition to its simplicity and ease of use, the technique does not require compensation of group velocity dispersion5-8 and does not induce photo-damage of the samples. This technique will be useful for characterization of ultrafast phase relaxation processes in material science, chemistry, and biology.